Difference Between Thermoplastic and Thermosetting Plastics

Whether you are having a car, watching television, gifting a toy to your child or even flying an aircraft, Plastic is everywhere. We can’t even think of our life without plastic.

In plastic part design often we come across this confusion about Thermoplastic vs Thermosetting plastic. So in this article, we will explain about Difference between thermoplastic and thermosetting plastics.

What is Plastic

Plastic or in the chemical term we call it “Polymer” is formed when multiple monomers bond together using a chemical reaction.

Molecules are bonded together to form plastics. Usually, monomers are made of carbon and hydrogen but they may also contain oxygen, nitrogen, and other gases.

Although there are natural polymers the recent industry trend is that businesses create their commercial polymers as per their need. This helps them to get the required mechanical and chemical properties in the said plastic.

Commercial plastics use additives, colors, fibers, and other chemicals to get enhanced properties that are suitable for different applications. In this article, we will find out the differences between Thermoplastics and thermosetting plastics.

Difference Between Thermoplastic and Thermosetting Plastics

This is the confusion among many engineers when they get into the plastic part design or plastic mold design. Although both sound similar both have a major difference in the way they respond when the heat is applied.

What is Thermoplastic

Thermoplastics are polymers that when heated get melted and form the desired shape. It can be re-melted and it can get a different shape.

So thermoplastic can be used and formed multiple times without hampering the chemical or mechanical properties up to some extent.

Thermoplastics are recyclable and can be used multiple times. The melting point is comparatively low. This kind of plastic offers more ductility and can absorb impact load very well. They are very sensitive to heat and are not used where extreme heat is encountered.

Most of the plastic that we see in our day-to-day life is Thermoplastic. 80% of the polymers found in the market are Thermoplastics.

Though it’s costlier than thermosetting due to its recycled nature and properties to mold into anything it is an ideal choice for industries.

Though thermoplastics can be melted and molded multiple times with each cycle it loses its properties. So there is a limit on how many times you can remold thermoplastics.

When we use re-melted plastics in the mold we call it regrind plastic. It’s an industry standard to use 10% regrind plastic and 90% virgin plastic in major applications.

Advantages Of Thermoplastics

  • Can be remolded multiple times
  • Can take any shape
  • Additives, colors, and fibers can be added easily
  • Regrind possible.
  • Reshaping capabilities available.
  • Offers good impact resistance
  • Usually chemical resistant
  • A superior finish is possible.
  • Can be molded with other polymers
  • Wide range of commercial applications.

Disadvantages of Thermoplastics

  • Not suitable for the high-temperature zone.
  • Not strong enough to withstand enough load
  • Regrind is possible only a few times.
  • Gets melts easily under heat
  • Costlier than thermosetting

Example of major commercial Thermoplastics

  • ABS- Acreno butadiene styrene
  • HIPS- High-impact polystyrene
  • PC- Polycarbonate
  • PE-Polieyhelene
  • PP-Polypropylene
  • PVC- Polyvinyl chloride
  • PS- Polystyrene
  • Nylon

What are Thermosetting plastics

Thermoset plastics get melted when the heat is applied and get the desired shape. However, it can not be remelted due to the cross-linking polymerization. Thermoset plastics once molded are unaffected by any solvent or heat.

Thermoset plastics are usually brittle and can not absorb impact loading, however, static loading capacity is great. So thermosets are usually used where static loading is of importance.

thermosetting plastics

Since Thermoset plastics can withstand heat, often those are used where extreme heat might get encountered like home appliances, electronic products, etc. This type of plastic is also used in sealant applications as they don’t deform over time or temperature.

It’s a recent trend to use Thermoset plastic over metal as the load-carrying capacity of thermosets can be compared with metals.

Though this type of transition is not very popular industries are moving away from metals to save on material cost and manufacturing cost.

Advantages of thermoset plastics

  • Can withstand enormous heat
  • Does not deform or melt when heat is applied
  • Excellent strength and load-carrying capacity.
  • An excellent option to replace metals.
  • Cost-effective plastic

Disadvantages of Thermoset plastics

  • Can not absorb impact loading
  • More brittle than ductile
  • Greater finishes are not possible.
  • Can not be remolded.
  • Can not be recycled.

Example of commercial Thermoset plastics

  • Melamine
  • Bakelite
  • Epoxy resins
  • Phenolic resins
  • Polyesters

Difference Between Thermoplastics And Thermosetting Plastics: Comparison

Sl #ThermoplasticsThermosetting
1They are liner polymersThey are crosslinked polymers
2Can be reused multiple timesCan not be reused
3Low melting pointHigh melting point
4Low strengthHigh strength
5High impact resistanceLow impact resistance
6Not fireproofUsually, fireproof up to some extent.
7Undergo chemical reactions during mouldingUndergo chemical reactions during molding
8Ductile in natureBrittle in nature
9Affected by solventNot affected by solvent
10Fewer varieties of plastics availableFewer varieties of plastics are available

Conclusion

Both thermoplastics and thermosets are widely used in commercial applications and both have their pros and cons. The primary difference between Thermoplastics and thermosetting plastics is how they respond to heat due to their chemical structure.

If there is one major difference that distinguishes both plastics is that Thermoplastic can be reused but Thermoset plastic can not be.

I hope you have a fair amount of idea about the difference between Thermoplastics and thermosetting plastics If you still have questions or doubts then do write in the comment section and we can take it forward from there.

Rajib
Rajib
Rajib Is The Founder And Head Of RiansClub. A NIT 2004 Graduate In Mechanical Engineering With Close To Two Decades Of Experience In Designing Large Appliances And Consumer Electronics Products.

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